Wednesday, 1 May 2013

At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?


At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Solution:
Mass of glucose, w =36 g
Osmotic pressure, π = 4.98 bar
Temperature, T = 300 K
Volume of solution, V = 1L
Formula of osmotic pressure

Plug the value and solve for R we get
R = π V/(nT) = 4.98 × 180/ (36 × 300)
R = 4.98/ 60  L atm K-1 mol– 1
Plug the value in second case we get
   
C = π/(RT)
Plug the values we get
 
C = 0.061 M

8 comments:

  1. can b done directly

    T = 300 K

    π = 1.52 bar

    R = 0.083 bar L K−1 mol−1

    Applying the relation,

    π= CRT
    C=π/RT
    C=1.52/(.083*300)

    = 0.061 mol

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    Replies
    1. from your method similar question is not solved

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  2. Replies
    1. Yes the answer 0.061M or 0.061mol/L means 0.61 moles in 1litre of solution= 0.61×180=10.98g or 11g(approx) since 180g is the molecular wt.of glucose. So the answer now becomes 11g/L.

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